En cliquant sur le bouton ci-dessous, vous pouvez consulter la liste des dernières publications scientifiques du laboratoire dans la "Collection HAL du M2P2" qui permet de faire des recherches par année, auteur, type de document (article scientifique, ouvrage, chapitre d'ouvrage, actes de conférence...), etc.
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Aymeric Fabien, Guillaume Lefebvre, Elisabeth Badens, Brice Calvignac, Damien Chaudanson, et al.. Contact angle of ethanol, water, and their mixtures on stainless steel surfaces in dense carbon dioxide. Journal of Colloid and Interface Science, 2024, 655, pp.535-545. ⟨10.1016/j.jcis.2023.10.163⟩. ⟨hal-04316090⟩ Plus de détails...
Hypothesis Contact angle can be a key parameter in chemical engineering. However, the development and the optimization of numerous processes using supercritical CO2, considered as environmentally friendly, requires new measurements under dense CO2 atmosphere. Besides, the influence of the roughness or the wetting regime on the contact angle is known at ambient conditions but remains to be discussed for systems under high pressure. Experimental Contact angle measurements of ethanol, water, and their mixtures, with ethanol mass fractions ranging from 0.25 to 0.75, on two stainless steels in saturated CO2 at pressures ranging from 0.1 MPa to 15.1 MPa, and at 313 K and 333 K were carried out in a set-up improving mass transfer between the studied liquid and the continuous fluid phase. Stainless steel surfaces have been characterized by atomic force and scanning electron microscopies allowing the application of the Wenzel equation. Findings Ethanol wetted totally both stainless steels while contact angles of all other liquids were increased by the rise of pressure, with contact angles up to 128 ° for water at 15.1 MPa. Trapped bubbles were observed at the solid/liquid interface and the bubble formation is discussed. Furthermore, the potential influence of bubble presence on the wetting regime is prospected through the question: could the pressure rise modify the wetting regime?
Aymeric Fabien, Guillaume Lefebvre, Elisabeth Badens, Brice Calvignac, Damien Chaudanson, et al.. Contact angle of ethanol, water, and their mixtures on stainless steel surfaces in dense carbon dioxide. Journal of Colloid and Interface Science, 2024, 655, pp.535-545. ⟨10.1016/j.jcis.2023.10.163⟩. ⟨hal-04316090⟩
J. Yang, A. Mouilleron, M. Monnot, C. Cordier, P. Moulin. Ultrafiltration for the biosecurity of fish production: The case of a sturgeon nursery. Aquacultural Engineering, 2023, 103, pp.102366. ⟨10.1016/j.aquaeng.2023.102366⟩. ⟨hal-04202096⟩ Plus de détails...
J. Yang, A. Mouilleron, M. Monnot, C. Cordier, P. Moulin. Ultrafiltration for the biosecurity of fish production: The case of a sturgeon nursery. Aquacultural Engineering, 2023, 103, pp.102366. ⟨10.1016/j.aquaeng.2023.102366⟩. ⟨hal-04202096⟩
Vénicia Numa, Christelle Crampon, Arnaud Bellon, Adil Mouahid, Elisabeth Badens. Valorization of food side streams by supercritical fluid extraction of compounds of interest from apple pomace. Journal of Supercritical Fluids, 2023, 202, pp.106056. ⟨10.1016/j.supflu.2023.106056⟩. ⟨hal-04294235⟩ Plus de détails...
Supercritical CO2 (scCO2) extraction, a green technology still little applied to side streams, has been used to explore the potential recovery of beneficial compounds from apple pomace, a food industry byproduct. The study examines the potential of scCO2 extraction on freeze-dried and airflow dried apple pomace, using laboratory-scale equipment with varying pressures (200–400 bar), temperatures (35–55 °C) with a fixed CO2 flow rate. Extracts were analyzed through LC-MS and GC-MS, while antioxidant capacity was assessed using the ABTS assay. The results were compared to those from Soxhlet n-hexane extraction. Optimal conditions of 300 bar and 55 °C with freeze-dried apple pomace yielded the highest mass loss. The main compounds identified included glyceryl dilinoleate, linoleic acid, and diacyl glycerol, with significant ursolic acid content. A preliminary higher scale feasibility test under optimal conditions demonstrated promising, duplicable outcomes, supporting prior claim that apple pomace contains valuable ingredients that can be reused in various industrial sectors.
Vénicia Numa, Christelle Crampon, Arnaud Bellon, Adil Mouahid, Elisabeth Badens. Valorization of food side streams by supercritical fluid extraction of compounds of interest from apple pomace. Journal of Supercritical Fluids, 2023, 202, pp.106056. ⟨10.1016/j.supflu.2023.106056⟩. ⟨hal-04294235⟩
Emilie Gout, Fatimatou Toure Lo, Mathias Monnot, Olivier Boutin, Pierre Vanloot, et al.. Coupling membrane processes with wet air oxidation for the remediation of industrial effluents. Chemical Engineering Journal, 2023, 472, pp.144937. ⟨10.1016/j.cej.2023.144937⟩. ⟨hal-04202142⟩ Plus de détails...
Emilie Gout, Fatimatou Toure Lo, Mathias Monnot, Olivier Boutin, Pierre Vanloot, et al.. Coupling membrane processes with wet air oxidation for the remediation of industrial effluents. Chemical Engineering Journal, 2023, 472, pp.144937. ⟨10.1016/j.cej.2023.144937⟩. ⟨hal-04202142⟩
Mathis Pasquier, Stéphane Jay, Jérôme Jacob, Pierre Sagaut. A Lattice-Boltzmann-Based Modelling Chain for Traffic-Related Atmospheric Pollutant Dispersion at the Local Urban Scale. Building and Environment, 2023, 242, pp.110562. ⟨10.1016/j.buildenv.2023.110562⟩. ⟨hal-04190005⟩ Plus de détails...
Urban traffic-related air pollution is a major source of environmental and health damage and is difficult to quantify due to its inherent physical complexity. We construct a CFD-based simulation framework coupling an efficient numerical method for turbulent fluid flows with a microscopic traffic model and an emissions model to simulate road transport pollutant dispersion at the urban microscale. We improve the open-source Lattice-Boltzmann based CFD software OpenLB to overcome its original stability deficiencies for high Reynolds number flows. A stable recursive regularization procedure with a double distribution function approach is proposed to solve an advection diffusion equation for passive scalar transport at high Reynolds number. The code is successfully validated on three reference cases of increasing complexity and the traffic model SUMO along with a physical engine emissions model are coupled with OpenLB to simulate traffic-induced pollution from a road network in a realistic complex geometry. Transient flow features are analysed and the time-averaged concentration levels in different neighbourhoods of the considered geometry are evaluated: high concentration levels are observed close to the streets but also inside specific building infrastructures due to complex wind dynamics. Analyses of altitudinal concentration variations show that flow recirculations located close to traffic lights can drive pollutant over the buildings and increase concentration levels inside inner courtyards. Time-averaged concentration maps are constructed using both spatially uniform and non-uniform line sources and it is shown that using uniform sources leads to up to 20% local concentration overestimations inside the urban canopy.
Mathis Pasquier, Stéphane Jay, Jérôme Jacob, Pierre Sagaut. A Lattice-Boltzmann-Based Modelling Chain for Traffic-Related Atmospheric Pollutant Dispersion at the Local Urban Scale. Building and Environment, 2023, 242, pp.110562. ⟨10.1016/j.buildenv.2023.110562⟩. ⟨hal-04190005⟩
Adrien Magne, Emilie Carretier, Lilivet Ubiera Ruiz, Thomas Clair, Morgane Le Hir, et al.. Recovery of Homogeneous Platinoid Catalysts from Pharmaceutical Media: Review on the Existing Treatments and the Perspectives of Membrane Processes. Membranes, 2023, 13 (8), pp.738. ⟨10.3390/membranes13080738⟩. ⟨hal-04202121⟩ Plus de détails...
Catalyst recovery is a major challenge for reaching the objectives of green chemistry for industry. Indeed, catalysts enable quick and selective syntheses with high reaction yields. This is especially the case for homogeneous platinoid catalysts which are almost indispensable for cross-coupling reactions often used by the pharmaceutical industry. However, they are based on scarce, expensive, and toxic resources. In addition, they are quite sensitive and degrade over time at the end of the reaction. Once degraded, their regeneration is complex and hazardous to implement. Working on their recovery could lead to highly effective catalytic chemistries while limiting the environmental and economic impacts of their one-time uses. This review aims to describe and compare conventional processes for metal removal while discussing their advantages and drawbacks considering the objective of homogeneous catalyst recovery. Most of them lead to difficulty recycling active catalysts due to their ability to only treat metal ions or to chelate catalysts without the possibility to reverse the mechanism. However, membrane processes seem to offer some perspectives with limiting degradations. While membranes are not systematically the best option for recycling homogeneous catalysts, current development might help improve the separation between pharmaceutical active ingredients and catalysts and enable their recycling.
Adrien Magne, Emilie Carretier, Lilivet Ubiera Ruiz, Thomas Clair, Morgane Le Hir, et al.. Recovery of Homogeneous Platinoid Catalysts from Pharmaceutical Media: Review on the Existing Treatments and the Perspectives of Membrane Processes. Membranes, 2023, 13 (8), pp.738. ⟨10.3390/membranes13080738⟩. ⟨hal-04202121⟩
L. Cappelli, N. Fedorczak, J. P. Gunn, S. Di Genova, J. Guterl, et al.. Study of the erosion and redeposition of W considering the kinetic energy distribution of incident ions through a semi-analytical model. Plasma Physics and Controlled Fusion, 2023, 65 (9), pp.095001. ⟨10.1088/1361-6587/ace282⟩. ⟨hal-04190861⟩ Plus de détails...
In today’s nuclear fusion devices, erosion of high-Z metallic plasma-facing materials (PFMs) is mainly caused by physical sputtering. That is, by the exchange of energy between plasma ions and the atoms in the walls. In most of the numerical codes currently in use impinging plasma is approximated as a fluid. By averaging the incident particles’ energy distribution the high-energy population of the eroded material is underestimated. For heavy materials such as W, high-energy eroded particles tend to ionize far from the wall and they are less affected by the sheath electric field hence, not being attracted back to the wall, they have a higher chance to contaminate the core plasma. This could in turn result in an underestimation of the net erosion sources. In this work, a semi-analytical model was developed to include the energy distribution of the incident particles. Then, by Monte Carlo method, the net erosion of tungsten from a smooth PFM was calculated. The results show that the kinetic description in energy is important only for incident particles ionized once. For instance, it is particularly important for plasma ions such as Deuterium. It is seen that Deuterium contribution to the W net sources is not always negligible if compared to light impurities or to tungsten self-sputtering in the range of plasma parameters tested. Finally, results show that the difference between the fluid and kinetic models becomes more pronounced for high-screening plasma conditions.
L. Cappelli, N. Fedorczak, J. P. Gunn, S. Di Genova, J. Guterl, et al.. Study of the erosion and redeposition of W considering the kinetic energy distribution of incident ions through a semi-analytical model. Plasma Physics and Controlled Fusion, 2023, 65 (9), pp.095001. ⟨10.1088/1361-6587/ace282⟩. ⟨hal-04190861⟩
In this study, we present a new approach for the growth monitoring of crystals using micro X-ray computed tomography (XCT). This technique allows us to track the evolution of the total crystal volume and surface in real time, and to calculate the growth rate. By segmenting the 3D XCT images using a robust method, we are able to extract detailed information about the crystals, such as their number, volume, diameter, and sphericity. Additionally, we determine the growth rates of individual crystal faces. Our method has the potential to greatly benefit the pharmaceutical and chemical industries, as it provides insight into the structural parameters of crystals during growth, which is crucial for optimization and control.
Gautier Hypolite, Jérôme Vicente, Hugo Taligrot, Philippe Moulin. X-ray tomography crystal characterization: Growth monitoring. Journal of Crystal Growth, 2023, 612, pp.127187. ⟨10.1016/j.jcrysgro.2023.127187⟩. ⟨hal-04071090⟩
Franck Corset, Mitra Fouladirad, Christian Paroissin. Imperfect condition-based maintenance for a gamma degradation process in presence of unknown parameters. Proceedings of the Institution of Mechanical Engineers, Part O: Journal of Risk and Reliability, 2023, 237 (3), pp.546-561. ⟨10.1177/1748006X221134132⟩. ⟨hal-04064988⟩ Plus de détails...
A system subject to degradation is considered. The degradation is modelled by a gamma process. A condition-based maintenance policy with perfect corrective and an imperfect preventive actions is proposed. The maintenance cost is derived considering a Markov-renewal process. The statistical inference of the degradation and maintenance parameters by the maximum likelihood method is investigated. A sensibility analysis to different parameters is carried out and the perspectives are detailed.
Franck Corset, Mitra Fouladirad, Christian Paroissin. Imperfect condition-based maintenance for a gamma degradation process in presence of unknown parameters. Proceedings of the Institution of Mechanical Engineers, Part O: Journal of Risk and Reliability, 2023, 237 (3), pp.546-561. ⟨10.1177/1748006X221134132⟩. ⟨hal-04064988⟩
Journal: Proceedings of the Institution of Mechanical Engineers, Part O: Journal of Risk and Reliability
A safe separation distance (SSD) needs to be considered during firefighting activities (fire suppression or people evacuation) against wildfires. The SSD is of critical interest for both humans and assets located in the wildland-urban interfaces (WUI). In most cases, the safety zone models and guidelines assume a flat terrain and only radiant heating. Nevertheless, injuries or damage do not result exclusively from radiant heating. Indeed, convection must be also considered as a significant contribution of heat transfer, particularly in the presence of the combined effects of sloping terrain and a high wind velocity. In this work, a critical case study is considered for the village of Sari-Solenzara in Corsica (France). This site location was selected by the operational staff since highintensity fire spread is likely to occur in the WUI during wind-blown conditions. This study was carried out for 4 m high shrubland, a sloping terrain of 12° and a wind speed of 16.6 m/s. The numerical simulations were performed using a fully physical fire model, namely, FireStar2D, to investigate a case of fire spreading, which is thought to be representative of most high wildfire risk situations in Corsica. This study is based on the evaluation of the total (radiative and convective) heat flux received by two types of targets (human bodies and buildings) located ahead of the fire front. The results obtained revealed that the radiation was the dominant heat transfer mode in the evaluation of the SSD. In addition, the predictions were consistent with the criterion established by the operational experts, which assumes that in Corsica, a minimum SSD of 50 m is required to keep an equipped firefighter without injury in a fuelbreak named ZAL. This numerical work also provides correlations relating the total heat flux to the SSD.
Jacky Fayad, Gilbert Accary, Frédéric Morandini, François-Joseph Chatelon, Lucile Rossi, et al.. Numerical Assessment of Safe Separation Distance in the Wildland-Urban Interfaces. Fire, 2023, 6 (209), ⟨10.3390/fire6050209⟩. ⟨hal-04101026⟩
