Traitement des effluents (voir les détails sur la page dédiée)
Publications scientifiques au M2P2
2023
Adrien Magne, Emilie Carretier, Lilivet Ubiera Ruiz, Thomas Clair, Morgane Le Hir, et al.. Recovery of Homogeneous Platinoid Catalysts from Pharmaceutical Media: Review on the Existing Treatments and the Perspectives of Membrane Processes. Membranes, 2023, 13 (8), pp.738. ⟨10.3390/membranes13080738⟩. ⟨hal-04202121⟩ Plus de détails...
Catalyst recovery is a major challenge for reaching the objectives of green chemistry for industry. Indeed, catalysts enable quick and selective syntheses with high reaction yields. This is especially the case for homogeneous platinoid catalysts which are almost indispensable for cross-coupling reactions often used by the pharmaceutical industry. However, they are based on scarce, expensive, and toxic resources. In addition, they are quite sensitive and degrade over time at the end of the reaction. Once degraded, their regeneration is complex and hazardous to implement. Working on their recovery could lead to highly effective catalytic chemistries while limiting the environmental and economic impacts of their one-time uses. This review aims to describe and compare conventional processes for metal removal while discussing their advantages and drawbacks considering the objective of homogeneous catalyst recovery. Most of them lead to difficulty recycling active catalysts due to their ability to only treat metal ions or to chelate catalysts without the possibility to reverse the mechanism. However, membrane processes seem to offer some perspectives with limiting degradations. While membranes are not systematically the best option for recycling homogeneous catalysts, current development might help improve the separation between pharmaceutical active ingredients and catalysts and enable their recycling.
Adrien Magne, Emilie Carretier, Lilivet Ubiera Ruiz, Thomas Clair, Morgane Le Hir, et al.. Recovery of Homogeneous Platinoid Catalysts from Pharmaceutical Media: Review on the Existing Treatments and the Perspectives of Membrane Processes. Membranes, 2023, 13 (8), pp.738. ⟨10.3390/membranes13080738⟩. ⟨hal-04202121⟩
Adrien Magne, Emilie Carretier, Lilivet Ubiera Ruiz, Thomas Clair, Morgane Le Hir, et al.. Recovery of Homogeneous Platinoid Catalysts from Pharmaceutical Media: Review on the Existing Treatments and the Perspectives of Membrane Processes. Membranes, 2023, 13 (8), pp.738. ⟨10.3390/membranes13080738⟩. ⟨hal-04543741⟩ Plus de détails...
Catalyst recovery is a major challenge for reaching the objectives of green chemistry for industry. Indeed, catalysts enable quick and selective syntheses with high reaction yields. This is especially the case for homogeneous platinoid catalysts which are almost indispensable for cross-coupling reactions often used by the pharmaceutical industry. However, they are based on scarce, expensive, and toxic resources. In addition, they are quite sensitive and degrade over time at the end of the reaction. Once degraded, their regeneration is complex and hazardous to implement. Working on their recovery could lead to highly effective catalytic chemistries while limiting the environmental and economic impacts of their one-time uses. This review aims to describe and compare conventional processes for metal removal while discussing their advantages and drawbacks considering the objective of homogeneous catalyst recovery. Most of them lead to difficulty recycling active catalysts due to their ability to only treat metal ions or to chelate catalysts without the possibility to reverse the mechanism. However, membrane processes seem to offer some perspectives with limiting degradations. While membranes are not systematically the best option for recycling homogeneous catalysts, current development might help improve the separation between pharmaceutical active ingredients and catalysts and enable their recycling.
Adrien Magne, Emilie Carretier, Lilivet Ubiera Ruiz, Thomas Clair, Morgane Le Hir, et al.. Recovery of Homogeneous Platinoid Catalysts from Pharmaceutical Media: Review on the Existing Treatments and the Perspectives of Membrane Processes. Membranes, 2023, 13 (8), pp.738. ⟨10.3390/membranes13080738⟩. ⟨hal-04543741⟩
Morgane Le Hir, Adrien Magne, Thomas Clair, Emilie Carretier, Philippe Moulin. Solvent Regeneration in Complex Mixture Using Pervaporation. Organic Process Research and Development, 2021, 25 (3), pp.469-485. ⟨10.1021/acs.oprd.0c00442⟩. ⟨hal-03515300⟩ Plus de détails...
This study aims to demonstrate the efficiency of dichloromethane (DCM) regeneration from a methanolic effluent by a combination of distillation and membrane pervaporation process. The presence of an azeotrope (MeOH/DCM/water) makes the regeneration of DCM via distillation alone impossible. A process simulation using ProSim software was carried out in order to evaluate the behavior of the azeotropic mixture. Two secondary treatments aiming to purify the DCM contained in the azeotrope were investigated. The first is the washing of the azeotrope with water. ProSim software was used to target the optimal conditions for washing before the experimental test. Residual water was recovered in the organic phase, meaning that the quality specifications for DCM were not reached. The second process studied for DCM purification was a pervaporation step. The feasibility of this had been proven at laboratory scale. The recovered DCM had the quality of a new solvent, and the whole process (distillation + pervaporation) reached a global DCM regeneration yield of 71.8% before optimization. This yield was limited by the distillation of methylal (also called dimethoxymethane) present in the methanolic effluent at the end of the distillation of the azeotrope, a compound retained by the pervaporation membrane. The pervaporation was performed on a hydrophilic Hybsi membrane letting methanol and water pass through and retaining the DCM (membrane surface = 0.15 m(2)). Optimization and scaling up were then carried out with a semi-industrial pervaporation pilot (membrane surface = 1.05 m(2)) which enabled the industrial scale-up. In order to facilitate the steering of the process and to ensure continuous and efficient monitoring of the regeneration operation, online monitoring by near-infrared probe (NIR) had been implemented allowing the composition of the mixture to be determined with an accuracy of +/- 0.05% on each compound. Finally, an assessment had been conducted of the regeneration pathways for methanol recovery at the bottom of the distillation column, for maximizing the regeneration of methanolic effluents by separating heavy compounds and methylal from methanol.
Morgane Le Hir, Adrien Magne, Thomas Clair, Emilie Carretier, Philippe Moulin. Solvent Regeneration in Complex Mixture Using Pervaporation. Organic Process Research and Development, 2021, 25 (3), pp.469-485. ⟨10.1021/acs.oprd.0c00442⟩. ⟨hal-03515300⟩
Morgane Le Hir, Adrien Magne, Thomas Clair, Emilie Carretier, Philippe Moulin. Solvent Regeneration in Complex Mixture Using Pervaporation. Organic Process Research and Development, 2021, 25 (3), pp.469-485. ⟨10.1021/acs.oprd.0c00442⟩. ⟨hal-03597582⟩ Plus de détails...
This study aims to demonstrate the efficiency of dichloromethane (DCM) regeneration from a methanolic effluent by a combination of distillation and membrane pervaporation process. The presence of an azeotrope (MeOH/DCM/water) makes the regeneration of DCM via distillation alone impossible. A process simulation using ProSim software was carried out in order to evaluate the behavior of the azeotropic mixture. Two secondary treatments aiming to purify the DCM contained in the azeotrope were investigated. The first is the washing of the azeotrope with water. ProSim software was used to target the optimal conditions for washing before the experimental test. Residual water was recovered in the organic phase, meaning that the quality specifications for DCM were not reached. The second process studied for DCM purification was a pervaporation step. The feasibility of this had been proven at laboratory scale. The recovered DCM had the quality of a new solvent, and the whole process (distillation + pervaporation) reached a global DCM regeneration yield of 71.8% before optimization. This yield was limited by the distillation of methylal (also called dimethoxymethane) present in the methanolic effluent at the end of the distillation of the azeotrope, a compound retained by the pervaporation membrane. The pervaporation was performed on a hydrophilic Hybsi membrane letting methanol and water pass through and retaining the DCM (membrane surface = 0.15 m(2)). Optimization and scaling up were then carried out with a semi-industrial pervaporation pilot (membrane surface = 1.05 m(2)) which enabled the industrial scale-up. In order to facilitate the steering of the process and to ensure continuous and efficient monitoring of the regeneration operation, online monitoring by near-infrared probe (NIR) had been implemented allowing the composition of the mixture to be determined with an accuracy of +/- 0.05% on each compound. Finally, an assessment had been conducted of the regeneration pathways for methanol recovery at the bottom of the distillation column, for maximizing the regeneration of methanolic effluents by separating heavy compounds and methylal from methanol.
Morgane Le Hir, Adrien Magne, Thomas Clair, Emilie Carretier, Philippe Moulin. Solvent Regeneration in Complex Mixture Using Pervaporation. Organic Process Research and Development, 2021, 25 (3), pp.469-485. ⟨10.1021/acs.oprd.0c00442⟩. ⟨hal-03597582⟩
Christophe Castel, Eric Favre, Sabine Rode, Emilie Carretier, Carole Arnal-Herault, et al.. Pervaporation : des matériaux membranaires aux procédés et à leurs applications. Techniques de l'Ingénieur, J2820 V2, p1-38, 2020. ⟨hal-03222910⟩ Plus de détails...
Christophe Castel, Eric Favre, Sabine Rode, Emilie Carretier, Carole Arnal-Herault, et al.. Pervaporation : des matériaux membranaires aux procédés et à leurs applications. Techniques de l'Ingénieur, J2820 V2, p1-38, 2020. ⟨hal-03222910⟩
Thomas La Rocca, Emilie Carretier, Didier Dhaler, Eric Louradour, Thien Truong, et al.. Purification of Pharmaceutical Solvents by Pervaporation through Hybrid Silica Membranes. Membranes, 2019, 9 (7), pp.76. ⟨10.3390/membranes9070076⟩. ⟨hal-02335018⟩ Plus de détails...
Solvents purification mainly used in pharmaceutical field such as acetone and methyl ethyl ketone (MEK) were performed through hybrid silica membranes and from binary and multi-components mixtures. Two hybrid silica membranes—zirconia doped bis(triethoxysilyl)methane and bis(triethoxysilyl)ethane (BTESE)—were studied. Flux, permeance, and separation factor were evaluated depending on temperature, composition, and number of organic compounds in the feed. Dehydration tests of acetone were operated at 30 and 45 °C following by acetone and MEK purification at 50 °C from multi-components hydro-organic mixtures where hydrophilic compounds (water, methanol) but also hydrophobic (dichloromethane (DCM) and/or toluene) were present. Results showed that the presence of Zr nanoparticles affected flux and improved selectivity in the case of dehydration. Experiments related to acetone and MEK purification, revealed a mass transfer alteration and a decrease of performance, from 99 to 97 wt% and from 98 to 95 wt% respectively, when the number of compounds in the initial feed grown up and more precisely, in the presence of DCM and toluene thus highlighting a possible coupling effect.
Thomas La Rocca, Emilie Carretier, Didier Dhaler, Eric Louradour, Thien Truong, et al.. Purification of Pharmaceutical Solvents by Pervaporation through Hybrid Silica Membranes. Membranes, 2019, 9 (7), pp.76. ⟨10.3390/membranes9070076⟩. ⟨hal-02335018⟩
Thomas La Rocca, Emilie Carretier, Thomas Clair, Martial Etienne, Philippe Moulin. On-Line NIR to Regulate Pervaporation Process: Application for Dehydration. Membranes, 2018, 8 (3), pp.74. ⟨hal-01947010⟩ Plus de détails...
The regeneration of volatile organic solvents via dehydration tests, from 90 wt %, was evaluated by pervaporation using an on-line near-infrared (NIR) spectrometer. Experiments were performed using a bis(triethoxysilyl)methane (BTESM)-based ceramic HybSi((R)) membrane at temperatures of 20, 30 and 40 degrees C. The presence of an on-line NIR allows continuous monitoring of the process without sampling, and quickly estimates mass fractions of species in the retentate. Dehydration tests were performed at 30 degrees C in order to confirm the on-line NIR reproducibility, and closely matched results obtained with an off-line densimeter. These results validated the usefulness of the on-line NIR and provided the same precision whatever the mass fraction in the retentate. A good on-line reproducibility was found, with an agreement between the on-line NIR and off-line densimeter, obtaining an average deviation of +/- 0.058 wt %, +/- 0.17 wt % and +/- 0.049 wt %, respectively, at 20, 30 and 40 degrees C.
Thomas La Rocca, Emilie Carretier, Thomas Clair, Martial Etienne, Philippe Moulin. On-Line NIR to Regulate Pervaporation Process: Application for Dehydration. Membranes, 2018, 8 (3), pp.74. ⟨hal-01947010⟩
S.A. Toudji, Jean-Philippe Bonnet, J-L. Gardarein, Emilie Carretier. New experimental setup for continuous mass flux measurement in pervaporation. Chemical Engineering Research and Design, 2017, 124 (1), pp.252 - 259. ⟨10.1016/j.cherd.2017.06.029⟩. ⟨hal-01590253⟩ Plus de détails...
Pervaporation is a separation process of liquid mixtures through a thin non-porous membrane. In vacuum pervaporation, the global mass flux is classically estimated by weighing the mass of permeate collected in cold traps. In this work, we propose a new experimental setup that allows a continuous measurement of the mass flux. The new mass flux method measurement was validated for single component permeation (ethanol and water) by comparing mass of permeate collected in cold traps with the level decrease of feed liquid measured with a pressure sensor. This new setup can be useful for laboratory studies dealing with the evolution of mass flux according to different parameters of the process as, for example, the permeate side pressure level or temperature of liquid feed.
S.A. Toudji, Jean-Philippe Bonnet, J-L. Gardarein, Emilie Carretier. New experimental setup for continuous mass flux measurement in pervaporation. Chemical Engineering Research and Design, 2017, 124 (1), pp.252 - 259. ⟨10.1016/j.cherd.2017.06.029⟩. ⟨hal-01590253⟩
Nicolas Combernoux, L. Schrive, V. Labed, Yvan Wyart, Emilie Carretier, et al.. Treatment of radioactive liquid effluents by reverse osmosis membranes: From lab-scale to pilot-scale. Water today, 2017, 123, pp.311-320. ⟨10.1016/j.watres.2017.06.062⟩. ⟨hal-01656412⟩ Plus de détails...
The recent use of the reverse osmosis (RO) process at the damaged Fukushima-Daiichi nuclear power plant generated a growing interest in the application of this process for decontamination purposes. This study focused on the development of a robust RO process for decontamination of two kinds of liquid effluents: a contaminated groundwater after a nuclear disaster and a contaminated seawater during a nuclear accident. The SW30 HR membrane was selected among other in this study due to higher retentions (96% for Cs and 98% for Sr) in a true groundwater. Significant fouling and scaling phenomenon, attributed to calcium and strontium precipitation, were evidenced in this work: this underscored the importance of the lab scale experiment in the process. Validation of the separation performances on trace radionuclides concentration was performed with similar retention around 96% between surrogates Cs (inactive) and 137Cs (radioactive). The scale up to a 2.6 m2 spiral wound membrane led to equivalent retentions (around 96% for Cs and 99% for Sr) but lower flux values: this underlined that the hydrodynamic parameters (flowrate/cross-flow velocity) should be optimized. This methodology was also applied on the reconstituted seawater effluent: retentions were slightly lower than for the groundwater and the same hydrodynamic effects were observed on the pilot scale. Then, ageing of the membrane through irradiation experiments were performed. Results showed that the membrane active layer composition influenced the membrane resistance towards γ irradiation: the SW30 HR membrane performances (retention and permeability) were better than the Osmonics SE at 1 MGy. Finally, to supplement the scale up approach, the irradiation of a spiral wound membrane revealed a limited effect on the permeability and retention. This indicated that irradiation conditions need to be controlled for a further development of the process.
Nicolas Combernoux, L. Schrive, V. Labed, Yvan Wyart, Emilie Carretier, et al.. Treatment of radioactive liquid effluents by reverse osmosis membranes: From lab-scale to pilot-scale. Water today, 2017, 123, pp.311-320. ⟨10.1016/j.watres.2017.06.062⟩. ⟨hal-01656412⟩
Fabrice Testa, Clémence Coetsier, Emilie Carretier, M. Ennahali, Benoit Laborie, et al.. Reused of Slurry By Membrane Processes for Microelectronic Industry. Water today, 2017, 123, pp.311-320. ⟨hal-01656407⟩ Plus de détails...
Fabrice Testa, Clémence Coetsier, Emilie Carretier, M. Ennahali, Benoit Laborie, et al.. Reused of Slurry By Membrane Processes for Microelectronic Industry. Water today, 2017, 123, pp.311-320. ⟨hal-01656407⟩
Philippe Moulin, Nicolas Combernoux, Luc Schrive, V. Labed, Y. Wyart, et al.. Treatment of Radioactive Liquid Effluents By Reverse Osmosis Membranes: From Lab-Scale to Pilot-Scale. Water Research, 2017, 123, pp.311-320. ⟨hal-01889583⟩ Plus de détails...
The recent use of the reverse osmosis (RO) process at the damaged Fukushima-Daiichi nuclear power plant generated a growing interest in the application of this process for decontamination purposes. This study focused on the development of a robust RO process for decontamination of two kinds of liquid effluents: a contaminated groundwater after a nuclear disaster and a contaminated seawater during a nuclear accident. The SW30 HR membrane was selected among other in this study due to higher retentions (96% for Cs and 98% for Sr) in a true groundwater. Significant fouling and scaling phenomenon, attributed to calcium and strontium precipitation, were evidenced in this work: this underscored the importance of the lab scale experiment in the process. Validation of the separation performances on trace radionuclides concentration was performed with similar retention around 96% between surrogates Cs (inactive) and 137Cs (radioactive). The scale up to a 2.6 m2 spiral wound membrane led to equivalent retentions (around 96% for Cs and 99% for Sr) but lower flux values: this underlined that the hydrodynamic parameters (flowrate/cross-flow velocity) should be optimized. This methodology was also applied on the reconstituted seawater effluent: retentions were slightly lower than for the groundwater and the same hydrodynamic effects were observed on the pilot scale. Then, ageing of the membrane through irradiation experiments were performed. Results showed that the membrane active layer composition influenced the membrane resistance towards γ irradiation: the SW30 HR membrane performances (retention and permeability) were better than the Osmonics SE at 1 MGy. Finally, to supplement the scale up approach, the irradiation of a spiral wound membrane revealed a limited effect on the permeability and retention. This indicated that irradiation conditions need to be controlled for a further development of the process.
Philippe Moulin, Nicolas Combernoux, Luc Schrive, V. Labed, Y. Wyart, et al.. Treatment of Radioactive Liquid Effluents By Reverse Osmosis Membranes: From Lab-Scale to Pilot-Scale. Water Research, 2017, 123, pp.311-320. ⟨hal-01889583⟩
Nicolas Combernoux, Luc Schrive, Véronique Labed, Yvan Wyart, Emilie Carretier, et al.. Irradiation effects on RO membranes: Comparison of aerobic and anaerobic conditions. Polymer Degradation and Stability, 2016, 134, pp.126-135. ⟨10.1016/j.polymdegradstab.2016.09.034⟩. ⟨hal-01461790⟩ Plus de détails...
In this study, the investigation of the degradation of polyamide composite reverse osmosis membrane under gamma irradiation was carried out in aerobic and anaerobic conditions. A gamma Co-60 source was used to reach irradiation doses ranging from 0.1 to 1 MGy, with a constant dose rate of 0.5 kGy h(-1). The RO membranes degradation was assessed using XPS and ATR-FTIR for the chemical modification of the membrane active layer. Ion chromatography, pH measurement and gas chromatography were also used to identify and quantify the species release in aqueous and gaseous phases. Results showed a difference in the degradation of the membrane active layer and support layer between aerobic and anaerobic conditions. The different analysis performed suggested that the breakage of amide bonds was significantly higher in aerobic conditions rather than in anaerobic. This observation was confirmed by the measurement of an increasing amount of release species in aqueous and gaseous phase in aerobic conditions. Ester bonds scissions were highlighted as soon as the dose reached the value of 0.1 MGy in both conditions indicating an important sensitivity of the PVA-type coating of the RO membrane towards irradiation. Nevertheless, investigation of the top 10 nm surface of the active layer composition by XPS showed that the scissions of amide and ester bonds were similar in both conditions. Finally, all these results underlined a difference in the degradation mechanisms of the RO membranes: in anaerobic conditions, the degradation was limited to the top surface of the membrane and reductive species were involved in the degradation reactions. (C) 2016 Elsevier Ltd. All rights reserved.
Nicolas Combernoux, Luc Schrive, Véronique Labed, Yvan Wyart, Emilie Carretier, et al.. Irradiation effects on RO membranes: Comparison of aerobic and anaerobic conditions. Polymer Degradation and Stability, 2016, 134, pp.126-135. ⟨10.1016/j.polymdegradstab.2016.09.034⟩. ⟨hal-01461790⟩
Nicolas Combernoux, Véronique Labed, Luc Schrive, Yvan Wyart, Emilie Carretier, et al.. Effect of gamma irradiation at intermediate doses on the performance of reverse osmosis membranes. International Journal for Radiation Physics and Chemistry, 2015, ⟨10.1016/j.radphyschem.2015.11.017⟩. ⟨hal-01294902⟩ Plus de détails...
The goal of this study is to explain the degradation of Polyamide (PA) composite reverse osmosis membrane (RO) in function of the irradiation dose. Irradiations were performed with a gamma 60Co source in wet conditions and under oxygen atmosphere. For different doses of 0.2 and 0.5 MGy with a constant dose rate of 0.5 kGy h−1, RO membranes performances (NaCl retention, permeability) were studied before and after irradiation. ATR-FTIR, ion chromatography and gas chromatography were used to characterize structural modification. Results showed that the permeability of RO membranes irradiated at 0.2 MGy exhibited a small decrease, related to scissions of the PVA coating. However, retention did not change at this dose. At 0.5 MGy, permeability showed a large increase of a factor around 2 and retention began to decrease from 99% to 95%. Chromatography measurements revealed a strong link between permselectivity properties variation, ion leakage and oxygen consumption. Add to ATR-FTIR observations, these results emphasized that the cleavages of amide and ester bonds were observed at 0.5 MGy, more precisely the loss of hydrogen bonds between polyamide chains. By different analysis, modifications of the polysulfone layer occur until a dose of 0.2 MGy.
Nicolas Combernoux, Véronique Labed, Luc Schrive, Yvan Wyart, Emilie Carretier, et al.. Effect of gamma irradiation at intermediate doses on the performance of reverse osmosis membranes. International Journal for Radiation Physics and Chemistry, 2015, ⟨10.1016/j.radphyschem.2015.11.017⟩. ⟨hal-01294902⟩
Journal: International Journal for Radiation Physics and Chemistry
Nicolas Combernoux, Luc Schrive, Véronique Labed, Yvan Wyart, Emilie Carretier, et al.. Study of polyamide composite reverse osmosis membrane degradation in water under gamma rays. Journal of Membrane Science, 2015, 480 (2), pp.64-73. ⟨10.1016/j.memsci.2015.01.019⟩. ⟨hal-01295140⟩ Plus de détails...
This study aims to investigate the impact of irradiation on the behavior of Polyamide (PA) composite reverse osmosis (RO) membranes. Irradiations were performed for two doses (0.1 and 1 MGy) in wet conditions under an oxygen atmosphere, with a gamma 60Co source. Irradiation effect on RO membranes performances (NaCl rejection, permeability) was studied before and after irradiation. ATR-FTIR, XPS, AFM, FESEM microscopy, ion chromatography were also used to characterize structural modifications. Results show that NaCl rejection of RO membranes irradiated at 1 MGy decreased until 64% and permeability increased by a factor of three. Nevertheless, membranes irradiated at 0.1 MGy did not exhibit any change in theirs permselectivity properties. Advanced analysis techniques confirmed that the firsts effects of gamma rays on RO membranes occurred between 0.1 and 1 MGy. Results emphasize that gamma rays effects on the RO membranes led to the breaking of amide and ester bonds at 1 MGy. These breakings resulted in loss of hydrogen bonds between polyamide chains, and consequently to a relaxation of the polyamide network. Finally, modifications of the polysulfone layer underneath were highlighted. Both relaxation of the polyamide network and modifications of the polysulfone layer could be involved in the drop of the permselectivity properties.
Nicolas Combernoux, Luc Schrive, Véronique Labed, Yvan Wyart, Emilie Carretier, et al.. Study of polyamide composite reverse osmosis membrane degradation in water under gamma rays. Journal of Membrane Science, 2015, 480 (2), pp.64-73. ⟨10.1016/j.memsci.2015.01.019⟩. ⟨hal-01295140⟩
Gregory Cano, Adil Mouahid, Emilie Carretier, Pascal Guasp, Didier Moulin, et al.. Computational fluid dynamics simulations of membrane filtration process adapted for water treatment of aerated sewage lagoons. Water Science and Technology, 2015, 71 (2), pp.197 - 202. ⟨10.2166/wst.2014.476⟩. ⟨hal-01916461⟩ Plus de détails...
Gregory Cano, Adil Mouahid, Emilie Carretier, Pascal Guasp, Didier Moulin, et al.. Computational fluid dynamics simulations of membrane filtration process adapted for water treatment of aerated sewage lagoons. Water Science and Technology, 2015, 71 (2), pp.197 - 202. ⟨10.2166/wst.2014.476⟩. ⟨hal-01916461⟩
Fabrice Testa, Clémence Coetsier, Emilie Carretier, M. Ennahali, B. Laborie, et al.. Recycling a slurry for reuse in chemical mechanical planarization of tungsten wafer: effect of chemical adjustments and comparison between static and dynamic experiments. Microelectronic Engineering, 2014, 113, pp.114-122. ⟨10.1016/j.mee.2013.07.022⟩. ⟨hal-01053254⟩ Plus de détails...
Recycling abrasive slurry that has been used in chemical mechanical polishing (CMP) is one of the options for reducing the cost of manufacturing microchip processors. We use ultrafiltration which is a method of choice to recycle silica (SiO2)-based slurry. Taking into account that the chemical composition of abrasive slurry plays an important role in tungsten CMP (W-CMP), chemical adjustments have to be made so that the concentrated after used slurry can be reused. In this study, we investigate the effects of chemical additives (iron catalyst, oxalic acid as complexing agent and surfactants as stabilizers) in slurry that has been retreated by ultrafiltration. Experiments are conducted both under static and dynamic conditions and results are compared to better understand the effect of chemical adjustments on the main performances of W-CMP. An optimal chemical adjustment is proposed through a design of experiments evaluation to obtain a concentrated after used and chemically adjust slurry comparable to the operational point of use slurry.
Fabrice Testa, Clémence Coetsier, Emilie Carretier, M. Ennahali, B. Laborie, et al.. Recycling a slurry for reuse in chemical mechanical planarization of tungsten wafer: effect of chemical adjustments and comparison between static and dynamic experiments. Microelectronic Engineering, 2014, 113, pp.114-122. ⟨10.1016/j.mee.2013.07.022⟩. ⟨hal-01053254⟩
Camille Regula, Emilie Carretier, Yvan Wyart, Geneviève Gésan-Guiziou, A. Vincent, et al.. Chemical cleaning/disinfection and ageing of organic UF membranes: a review. Water Research, 2014, 56, pp.325-365. ⟨10.1016/j.watres.2014.02.050⟩. ⟨hal-01053262⟩ Plus de détails...
Membrane separation processes have become a basic unit operation for process design and product development. These processes are used in a variety of separation and concentration steps, but in all cases, the membranes must be cleaned regularly to remove both organic and inorganic material deposited on the surface and/or into the membrane bulk. Cleaning/disinfection is a vital step in maintaining the permeability and selectivity of the membrane in order to get the plant to its original capacity, to minimize risks of bacteriological contamination, and to make acceptable products. For this purpose, a large number of chemical cleaning/disinfection agents are commercially available. In general, these cleaning/disinfection agents have to improve the membrane flux to a certain extent. However, they can also cause irreversible damages in membrane properties and performances over the long term. Until now, there is considerably less literature dedicated to membrane ageing than to cleaning/disinfection. The knowledge in cleaning/disinfection efficiency has recently been improved. But in order to develop optimized cleaning/disinfection protocols there still remains a challenge to better understand membrane ageing. In order to compensate for the lack of correlated cleaning/disinfection and ageing data from the literature, this paper investigates cleaning/disinfection efficiencies and ageing damages of organic ultrafiltration membranes. The final aim is to provide less detrimental cleaning/disinfection procedures and to propose some guidelines which should have been taken into consideration in term of membrane ageing studies. To carry out this study, this article will detail the background of cleaning/disinfection and aging membrane topics in a first introductive part. In a second part, key factors and endpoints of cleaning/disinfection and aging membranes will be discussed deeply: the membrane role and the cleaning parameters roles, such as water quality, storing conditions, cleaning/disinfection/aging agents/conditions/protocols. The third and last part will be developed the parameters, methods and ways of characterization at our disposal and commonly used to develop and implement membrane cleaning and/or ageing studies.
Camille Regula, Emilie Carretier, Yvan Wyart, Geneviève Gésan-Guiziou, A. Vincent, et al.. Chemical cleaning/disinfection and ageing of organic UF membranes: a review. Water Research, 2014, 56, pp.325-365. ⟨10.1016/j.watres.2014.02.050⟩. ⟨hal-01053262⟩
Philippe Moulin, Camille Regula, Emilie Carretier, Yvan Wyart, M. Sergent, et al.. Influence of commercial detergents on UF membrane ageing: case of drinking water. Medical Engineering & Physics, 2013, 4 (1), pp.27-51. ⟨10.12989/mwt.2013.4.1.027⟩. ⟨hal-00995692⟩ Plus de détails...
During cleaning steps, ultrafiltration membranes are mechanically and chemically stressed. This may result in membrane degradations and failures. In this paper, polysulfone membranes were used to evaluate membrane deteriorations by commercial detergents in static conditions. Ageing of the membrane was simulated by immersing samples in solutions containing commercial detergents with various concentrations, temperatures and times defined by experimental designs. Indeed, an innovative approach in the chemical membranes ageing researches, based on methodological tools, was used in order to achieve significant ageing experiments without using an accelerated ageing protocol. The macroscopic changes were monitored by permeability measurements and mechanical strength tests coupled with a microscopic characterization by ATR-FTIR and HRSEM. The present work details results obtained for three commercial detergents: an alkaline, an acidic and an enzymatic detergent. It was found that the detergents used in the industrial advised conditions (concentration, temperature and time of contact) were not detrimental for membrane properties (permeability and elongation at break) and so for the quality of the produced water. Over the industrial cumulated time of contact, different ageing effects can be observed and compared with the ones induced by NaOCl.
Philippe Moulin, Camille Regula, Emilie Carretier, Yvan Wyart, M. Sergent, et al.. Influence of commercial detergents on UF membrane ageing: case of drinking water. Medical Engineering & Physics, 2013, 4 (1), pp.27-51. ⟨10.12989/mwt.2013.4.1.027⟩. ⟨hal-00995692⟩
Philippe Moulin, Camille Regula, Emilie Carretier, Geneviève Gésan-Guiziou, Michelle Sergent, et al.. Influence of commercial detergents on UF membrane ageing: Case of drinking water. Membrane Water Treatment, 2013. ⟨hal-01916481⟩ Plus de détails...
Philippe Moulin, Camille Regula, Emilie Carretier, Geneviève Gésan-Guiziou, Michelle Sergent, et al.. Influence of commercial detergents on UF membrane ageing: Case of drinking water. Membrane Water Treatment, 2013. ⟨hal-01916481⟩
Camille Regula, Emilie Carretier, Yvan Wyart, Michel Sergent, Geneviève Gésan-Guiziou, et al.. Influence of commercial detergents on UF membrane ageing: Case of ă drinking water. Membrane Water Treatment, 2013, 4 (1), pp.27-51. ⟨hal-01464726⟩ Plus de détails...
During cleaning steps, ultrafiltration membranes are mechanically and ă chemically stressed. This may result in membrane degradations and ă failures. In this paper, polysulfone membranes were used to evaluate ă membrane deteriorations by commercial detergents in static conditions. ă Ageing of the membrane was simulated by immersing samples in solutions ă containing commercial detergents with various concentrations, ă temperatures and times defined by experimental designs. Indeed, an ă innovative approach in the chemical membranes ageing researches, based ă on methodological tools, was used in order to achieve significant ageing ă experiments without using an accelerated ageing protocol. The ă macroscopic changes were monitored by permeability measurements and ă mechanical strength tests coupled with a microscopic characterization by ă ATR-FTIR and HRSEM. The present work details results obtained for three ă commercial detergents: an alkaline, an acidic and an enzymatic ă detergent. It was found that the detergents used in the industrial ă advised conditions (concentration, temperature and time of contact) were ă not detrimental for membrane properties (permeability and elongation at ă break) and so for the quality of the produced water. Over the industrial ă cumulated time of contact, different ageing effects can be observed and ă compared with the ones induced by NaOCl.
Camille Regula, Emilie Carretier, Yvan Wyart, Michel Sergent, Geneviève Gésan-Guiziou, et al.. Influence of commercial detergents on UF membrane ageing: Case of ă drinking water. Membrane Water Treatment, 2013, 4 (1), pp.27-51. ⟨hal-01464726⟩
Camille Regula, Emilie Carretier, Yvan Wyart, M. Sergent, Geneviève Gésan-Guiziou, et al.. Drinking water ultrafiltration: state of the art and experimental designs approach. Desalination and Water Treatment, 2013, 51 (25-27), pp.4892-4900. ⟨10.1080/19443994.2013.795213⟩. ⟨hal-00995678⟩ Plus de détails...
During cleaning steps, ultrafiltration membranes are mechanically and chemically stressed. This can result in membrane degradations, failures, and be shut down for membrane replacement and therefore affect the production rate of the process and its sustainability. These phenomena raise the problem of necessary optimization of the cleaning procedures that have to tackle simultaneously, the best cleaning efficiency and the less detrimental procedures for the membranes. Despite the fact that aging is becoming a major issue between end-users, membrane manufacturers, and chemical product suppliers, there is considerably less literature dedicated to membrane aging than to cleaning. First, this study briefly reviews articles dedicated to aging damages involved by NaOCl and commercial detergents (especially on polysulfone ultrafiltration membrane). Then, the present study details the innovative way setup: "Designs of experiments" is used to provide additional data that help with a thorough understanding of membrane aging. Thus, contrary to the accelerated aging approach that is commonly used in membrane-aging researches (concentration per time of contact: "c × t parameter"), designs of experiments were used to organize at best the aging experiments in order to achieve a relevant establishment of an aging pattern. Results show that this scientific approach provides a satisfying and reliable pattern to simulate membrane aging in function of the chosen chemical parameters.
Camille Regula, Emilie Carretier, Yvan Wyart, M. Sergent, Geneviève Gésan-Guiziou, et al.. Drinking water ultrafiltration: state of the art and experimental designs approach. Desalination and Water Treatment, 2013, 51 (25-27), pp.4892-4900. ⟨10.1080/19443994.2013.795213⟩. ⟨hal-00995678⟩
C. Regula, Emilie Carretier, Yvan Wyart, M. Sergent, Geneviève Gésan-Guiziou, et al.. Ageing of ultrafiltration membranes in contact with sodium hypochlorite and commercial oxidant: experimental designs as a new ageing protocol. Separation and Purification Technology, 2013, 103, pp.119-138. ⟨10.1016/j.seppur.2012.10.010⟩. ⟨hal-00996093⟩ Plus de détails...
In drinking water production plants using membrane processes, contact with cleaning chemicals is believed to play an important role in membrane ageing. In this article, polysulfone membranes were used to simulate the industrial cleaning in static conditions. Ageing of the membrane was mimicked by immersing samples in solutions containing sodium hypochlorite and commercial oxidants with various concentrations, temperatures and soaking times defined by experimental designs. For the first time in the chemical membranes ageing research, an approach based on methodological tools has been realized. The main interest is to achieve a relevant ageing pattern without using an accelerated ageing protocol (high concentrations and short contact times). The macroscopic changes were monitored by permeability measurement and mechanical strength tests coupled with a microscopic characterization by ATR-FTIR (to identify the chemical functional groups affected by ageing) and SEM (to visualize qualitatively the surface changes and deteriorations). The present work details the comparison between NaOCl and another oxidant: P3-Oxysan ZS (composed of peracetic and peroctanoic acid). The comparison of the macroscopic and microscopic properties of hypochlorite-aged membranes and P3-Oxysan ZS-aged membrane indicate NaOCl is far more detrimental for membrane integrity than P3-Oxysan ZS. The latter might give an alternative solution to the use of chlorine on industrial plant. The obtained results let to consider less harmful cleaning products on membranes. Then, the present study based on experimental designs let to underline that the most commonly used parameter "concentration × time of exposure" (c × t) was not a representative tool to predict membrane ageing.
C. Regula, Emilie Carretier, Yvan Wyart, M. Sergent, Geneviève Gésan-Guiziou, et al.. Ageing of ultrafiltration membranes in contact with sodium hypochlorite and commercial oxidant: experimental designs as a new ageing protocol. Separation and Purification Technology, 2013, 103, pp.119-138. ⟨10.1016/j.seppur.2012.10.010⟩. ⟨hal-00996093⟩
Emilie Carretier, H. Marteau, Philippe Moulin. Development of a nuclearized pilot for the purification of radioactive water: dead end filtration with ceramic membrane. Procedia Engineering, 2012, 44, pp.1718-1720. ⟨10.1016/j.proeng.2012.08.921⟩. ⟨hal-00997167⟩ Plus de détails...
Emilie Carretier, H. Marteau, Philippe Moulin. Development of a nuclearized pilot for the purification of radioactive water: dead end filtration with ceramic membrane. Procedia Engineering, 2012, 44, pp.1718-1720. ⟨10.1016/j.proeng.2012.08.921⟩. ⟨hal-00997167⟩
C. Regula, Emilie Carretier, Yvan Wyart, M. Sergent, Geneviève Gésan-Guiziou, et al.. Ageing of polysulfone ultrafiltation membranes for drinking water production in contact with sodium hypochlorite or formulated detergents. Procedia Engineering, 2012, 44, pp.1038-1040. ⟨10.1016/j.proeng.2012.08.668⟩. ⟨hal-01026337⟩ Plus de détails...
C. Regula, Emilie Carretier, Yvan Wyart, M. Sergent, Geneviève Gésan-Guiziou, et al.. Ageing of polysulfone ultrafiltation membranes for drinking water production in contact with sodium hypochlorite or formulated detergents. Procedia Engineering, 2012, 44, pp.1038-1040. ⟨10.1016/j.proeng.2012.08.668⟩. ⟨hal-01026337⟩
Georgette Rebollar-Perez, Emilie Carretier, Nicolas Lesage, Philippe Moulin. Vapour permeation of VOC emitted from petroleum activities: application for low concentrations. Journal of Industrial and Engineering Chemistry, 2012, 18 (4), pp.1339-1352. ⟨10.1016/j.jiec.2012.01.039⟩. ⟨hal-00997230⟩ Plus de détails...
This study deals with the application of vapour permeation on the abatement of air polluted with VOC, from low to medium concentrations. Toluene, butadiene and propylene were chosen as model compounds. On a first part of the study, the permeation of single VOC, binary and ternary VOC/air mixtures was performed at different flow rates and VOC concentrations. The permeate flux, permeance, enrichment factor, separation efficiency and the recovery were determined. The experimental results were compared to those obtained with a mathematical model, allowing the calculation of the membrane area required to eliminate 95% of the feed VOC content.
Georgette Rebollar-Perez, Emilie Carretier, Nicolas Lesage, Philippe Moulin. Vapour permeation of VOC emitted from petroleum activities: application for low concentrations. Journal of Industrial and Engineering Chemistry, 2012, 18 (4), pp.1339-1352. ⟨10.1016/j.jiec.2012.01.039⟩. ⟨hal-00997230⟩
Journal: Journal of Industrial and Engineering Chemistry
Fanny Springer, Emilie Carretier, D. Veyret, D. Dhaler, Philippe Moulin. Numerical and experimental methodology for the development of a new membrane prototype intended to microfiltration bioprocesses. Application to milk filtration. Chemical Engineering and Processing: Process Intensification, 2011, 50 (9), pp.904-915. ⟨10.1016/j.cep.2011.07.009⟩. ⟨hal-01026357⟩ Plus de détails...
In tangential flow filtration, the non-uniform TransMembrane Pressure (TMP) on the membrane length produces a non homogeneous filtration cake, initiates process selectivity changes and modifies the permeate quality. The purpose of this study is to create a tubular ceramic membrane prototype with a more uniform TMP, intended to filtration of fouling fluids. The principle of this membrane structure is to waterproof the external membrane surface to limit flow circulation in the porous support of the membrane. The production was controlled by sizing "permeation vents". This development was achieved using a CFD modelling tool interacting with experiments. A preliminary modelling study was made with water. This work was afterwards applied to the industrial process of casein micelle separation from skim milk. The influence of operating conditions on the membrane hydrodynamics was highlighted. The modelling results were experimentally confirmed, with a discrepancy smaller than 3% and a reproducible water permeability of 2.3 L h−1 bar−1 for 1 mm-wide vent (TMP = 1 bar, T = 20 °C). Then, milk filtration experiments showed a production ratio milk/water equal to 1/2. The permeate quality parameters were studied and the fouling phenomena were taken into account. A parametric study led to the sizing of a final prototype. Its efficiency was experimentally evaluated.
Fanny Springer, Emilie Carretier, D. Veyret, D. Dhaler, Philippe Moulin. Numerical and experimental methodology for the development of a new membrane prototype intended to microfiltration bioprocesses. Application to milk filtration. Chemical Engineering and Processing: Process Intensification, 2011, 50 (9), pp.904-915. ⟨10.1016/j.cep.2011.07.009⟩. ⟨hal-01026357⟩
Journal: Chemical Engineering and Processing: Process Intensification
Georgette Rebollar-Perez, Emilie Carretier, Nicolas Lesage, Philippe Moulin. Volatile Organic Compound (VOC) removal by vapor permeation at low VOC concentrations: laboratory scale results and modeling for scale up. Membranes, 2011, 1 (1), pp.80-90. ⟨10.3390/membranes1010080⟩. ⟨hal-01026399⟩ Plus de détails...
Petroleum transformation industries have applied membrane processes for solvent and hydrocarbon recovery as an economic alternative to reduce their emissions and reuse evaporated components. Separation of the volatile organic compounds (VOCs) (toluene-propylene-butadiene) from air was performed using a poly dimethyl siloxane (PDMS)/α-alumina membrane. The experimental set-up followed the constant pressure/variable flow set-up and was operated at ~21 °C. The membrane is held in a stainless steel module and has a separation area of 55 × 10−4 m². Feed stream was set to atmospheric pressure and permeate side to vacuum between 3 and 5 mbar. To determine the performance of the module, the removed fraction of VOC was analyzed by Gas Chromatography/Flame Ionization Detector (GC/FID). The separation of the binary, ternary and quaternary hydrocarbon mixtures from air was performed at different flow rates and more especially at low concentrations. The permeate flux, permeance, enrichment factor, separation efficiency and the recovery extent of the membrane were determined as a function of these operating conditions. The permeability coefficients and the permeate flux through the composite PDMS-alumina membrane follow the order given by the Hildebrand parameter: toluene > 1,3-butadiene > propylene. The simulated data for the binary VOC/air mixtures showed fairly good agreement with the experimental results in the case of 1,3-butadiene and propylene. The discrepancies observed for toluene permeation could be minimized by taking into account the effects of the porous support and an influence of the concentration polarization. Finally, the installation of a 0.02 m2 membrane module would reduce 95% of the VOC content introduced at real concentration conditions used in the oil industry.
Georgette Rebollar-Perez, Emilie Carretier, Nicolas Lesage, Philippe Moulin. Volatile Organic Compound (VOC) removal by vapor permeation at low VOC concentrations: laboratory scale results and modeling for scale up. Membranes, 2011, 1 (1), pp.80-90. ⟨10.3390/membranes1010080⟩. ⟨hal-01026399⟩
Clémence Coetsier, Fabrice Testa, Emilie Carretier, M. Ennahali, B. Laborie, et al.. Static dissolution rate of tungsten film versus chemical adjustments of a reused slurry for chemical mechanical polishing. Applied Surface Science, 2011, 257 (14), pp.6163-6170. ⟨10.1016/j.apsusc.2011.02.023⟩. ⟨hal-01026413⟩ Plus de détails...
Tungsten is widely used as deposited layer for the multi-level interconnection structures of wafers. The chemical composition of abrasive slurry plays an important role in chemical mechanical polishing (CMP) process. Removal of tungsten is driven by complex oxidation mechanisms between slurry components. The slurry for tungsten CMP generally contains oxidizer, iron catalyst, complexing agents and stabilizers in a pH adjusted solution of abrasive particles. Interaction between iron complex and H2O2 in the slurry is the main factor governing the chemical mode of material removal, oxidation potencies and kinetics. In this study, we investigate the effects of chemical additives in silica (SiO2)-based slurry on the removal rate of the tungsten film. Experiments were carried out in static batch as a preliminary study to understand and optimize chemical mechanisms in CMP-Tungsten process. Experiment designs were conducted to understand the influence of the chemical additives on the main performances of W-CMP. Used slurry, concentrated and retreated with chemical adjustments, is compared to the original slurry as a reference.
Clémence Coetsier, Fabrice Testa, Emilie Carretier, M. Ennahali, B. Laborie, et al.. Static dissolution rate of tungsten film versus chemical adjustments of a reused slurry for chemical mechanical polishing. Applied Surface Science, 2011, 257 (14), pp.6163-6170. ⟨10.1016/j.apsusc.2011.02.023⟩. ⟨hal-01026413⟩
Fabrice Testa, Clémence Coetsier, Emilie Carretier, M. Ennahali, B. Laborie, et al.. Retreatment of silicon slurry by membrane processes. Journal of Hazardous Materials, 2011, 192 (2), pp.440-450. ⟨10.1016/j.jhazmat.2011.05.016⟩. ⟨hal-01026376⟩ Plus de détails...
The purpose of the present study is to develop a process to regenerate the polish liquid used in Chemical and Mechanical Polishing (CMP), called "slurry", and more specifically Silicon CMP slurry. Physico-chemical analyses show a considerable dilution of slurry through washing waters used in polishing. Thus, this effluent has been characterised for a better identification of the deviations from the slurry of reference (Point Of Use). Hence, the principle is to regenerate this effluent by membrane processes. The ultrafiltration results obtained at laboratory scale have led to the development of an industrial prototype. An optimal utilisation of this treatment allows completing a two-step process: the reconcentration by ultrafiltration and a chemical adjustment by addition of concentrated slurry. A stable behaviour of the slurry at the different steps of the process has been observed. Polishing results are similar with retreated and POU slurries. Furthermore, the functioning at industrial scale permits to maintain the performances obtained on the laboratory pilot.
Fabrice Testa, Clémence Coetsier, Emilie Carretier, M. Ennahali, B. Laborie, et al.. Retreatment of silicon slurry by membrane processes. Journal of Hazardous Materials, 2011, 192 (2), pp.440-450. ⟨10.1016/j.jhazmat.2011.05.016⟩. ⟨hal-01026376⟩
F. Springer, R. Ghidossi, E. Carretier, D. Veyret, D. Dhaler, et al.. Study of the Effect of Geometry on Wall Shear Stress and Permeate Flux for Ceramic Membranes: CFD and Experimental Approaches. Engineering Applications of Computational Fluid Mechanics, 2010, 4 (1), pp.17-28. ⟨10.1080/19942060.2010.11015296⟩. ⟨hal-01295364⟩ Plus de détails...
Knowing how wall shear stress develops at the membrane surface is extremely useful when trying to reduce concentration polarization and fouling. Newly developed as well as manufactured ceramic membranes exhibit various channel geometries (cylindrical, square, triangular, etc). Mass transport characteristics depend on the geometry that conditions hydrodynamic conditions. The goal of this work is to study the influence of the channel geometry on the wall shear stress for various operating parameters (tangential velocity, transmembrane pressure…). Numerical simulations are performed for various inlet velocities for different channel geometries. The wall shear stress along the channel perimeter as a function of the shape and the cross section of the channel are studied. The influence of the geometry on the membrane performances is also studied. The simulated shear stress is employed to correlate experimental results. The results of this comparison show that mass transfer resistance depends on the wall shear stress alone, regardless of the flow rate, the shape or section of the channels.
F. Springer, R. Ghidossi, E. Carretier, D. Veyret, D. Dhaler, et al.. Study of the Effect of Geometry on Wall Shear Stress and Permeate Flux for Ceramic Membranes: CFD and Experimental Approaches. Engineering Applications of Computational Fluid Mechanics, 2010, 4 (1), pp.17-28. ⟨10.1080/19942060.2010.11015296⟩. ⟨hal-01295364⟩
Journal: Engineering Applications of Computational Fluid Mechanics
Georgette Rebollar-Perez, Emilie Carretier, Philippe Moulin. Aplicaciones de la permeación de vapor: el tratamiento de compuestos orgánicos volátiles de origen antropogénico. Revista mexicana de ingeniería química, 2010, 9 (1), pp.67-77. ⟨hal-01044472⟩ Plus de détails...
Vapour permeation is a membrane separating process that has been used since several decades for gas separation and it has been recently and successfully applied in treatment of volatile organic compounds (VOC) charged gaseous effluents. It presents several advantages compared to conventional processes for gas effluent treatment (e.g. adsorption, incineration and oxidation): it is energetically less demanding, it is easy to operate and it is economically feasible. This article presents a review of the VOC emissions in some principal industrialised countries and the positioning of vapour permeation between the processes for gaseous effluent treatment. It also presents some generalities about the operational principles of vapour permeation, as well as the main characteristics of the commonly used membrane modules and the current materials used for membrane manufacturing. Finally, an overview of the industrial application opportunities of vapour permeation is given.
Georgette Rebollar-Perez, Emilie Carretier, Philippe Moulin. Aplicaciones de la permeación de vapor: el tratamiento de compuestos orgánicos volátiles de origen antropogénico. Revista mexicana de ingeniería química, 2010, 9 (1), pp.67-77. ⟨hal-01044472⟩
R. Ghidossi, Emilie Carretier, D. Veyret, D. Dhaler, Philippe Moulin. Optimizing the compacity of ceramic membranes. Journal of Membrane Science, 2010, 360 (1-2), pp.483-492. ⟨10.1016/j.memsci.2010.05.050⟩. ⟨hal-01024773⟩ Plus de détails...
The aim of this study is to increase exchange area or specific area of the membrane unit containing the ceramic membranes in order to achieve a compacity of over 330 m2/m3. Several configurations were studied by varying parameters like the diameter, membrane geometry, and the form of channels (cylindrical, square-section, triangular, hexagonal, etc.). Taking manufacturing constraints into account, several optimized geometries were described, thus allowing the optimization of the filtration area for each module. In this way, membrane compacity was significantly improved. Therefore a substantial increase in the permeate flux was expected and it was important to verify the capacity of the porous media to evacuate such permeate flux. Computational fluid dynamics analysis was used to simulate permeate evacuation as well as the flow-rate of each individual channel in the monolith. The optimal geometries could then be determined as a function of this permeate flow-rate and/or cut-off threshold. The experimental results obtained with water were in good agreement with those obtained by numerical simulation.
R. Ghidossi, Emilie Carretier, D. Veyret, D. Dhaler, Philippe Moulin. Optimizing the compacity of ceramic membranes. Journal of Membrane Science, 2010, 360 (1-2), pp.483-492. ⟨10.1016/j.memsci.2010.05.050⟩. ⟨hal-01024773⟩
F. Springer, Remy Ghidossi, Emilie Carretier, Damien Veyret, D. Dhaler, et al.. Study of the effect of geometry on wall shear stress and permeate flux for ceramic membranes: CFD and experimental approaches. Engineering Applications of Computational Fluid Mechanics, 2010, 4 (1), pp.17-29. ⟨hal-01025200⟩ Plus de détails...
F. Springer, Remy Ghidossi, Emilie Carretier, Damien Veyret, D. Dhaler, et al.. Study of the effect of geometry on wall shear stress and permeate flux for ceramic membranes: CFD and experimental approaches. Engineering Applications of Computational Fluid Mechanics, 2010, 4 (1), pp.17-29. ⟨hal-01025200⟩
Journal: Engineering Applications of Computational Fluid Mechanics
E. Barbot, E. Carretier, Y. Wyart, B. Marrot, Philippe Moulin. Transportable membrane process to produce drinking water. Desalination, 2009, 248 (1-3), pp.58 - 63. ⟨10.1016/j.desal.2008.05.038⟩. ⟨hal-01916716⟩ Plus de détails...
E. Barbot, E. Carretier, Y. Wyart, B. Marrot, Philippe Moulin. Transportable membrane process to produce drinking water. Desalination, 2009, 248 (1-3), pp.58 - 63. ⟨10.1016/j.desal.2008.05.038⟩. ⟨hal-01916716⟩
Fanny Springer, Remy Ghidossi, Emilie Carretier, Damien Veyret, Didier Dhaler, et al.. Determination of the Wall Shear Stress by Numerical Simulation: Membrane Process Applications. Chemical Product and Process Modeling, 2009, 4 (4), 10 p. ⟨10.2202/1934-2659.1328⟩. ⟨hal-01916729⟩ Plus de détails...
Membrane processes have been intensely developing during the last decades, and mainly in dairy industry. Considering the feed effluent complexity, concentration polarization phenomenon and fouling are accentuated limitations for the development of membrane dairy filtration processes. Knowledge of the wall shear stress developed at the membrane surface is fundamental to reduce those phenomena. In this work, the variation of the wall shear stress on cylindrical, square, triangular and hybrid channels by numerical simulation for various operating parameters was studied. Predictions were established for different commercial ceramic membranes and predict the geometry that tends to better mass transport efficiency by enhancing hydrodynamics conditions. Numerical simulations are performed over a typical range of Reynolds numbers inside different channel geometries under laminar and turbulent conditions. Consequently, this paper intended to enhance the performances of these processes by maximizing the average wall shear stress on the membrane surface by numerical simulation. A comparison with experimental results was realized and a good agreement was obtained. Given those conclusions, a new membrane according to the whole CFD results consistent with experimental results was designed.
Fanny Springer, Remy Ghidossi, Emilie Carretier, Damien Veyret, Didier Dhaler, et al.. Determination of the Wall Shear Stress by Numerical Simulation: Membrane Process Applications. Chemical Product and Process Modeling, 2009, 4 (4), 10 p. ⟨10.2202/1934-2659.1328⟩. ⟨hal-01916729⟩
Philippe Moulin, Fanny Springer, Emilie Carretier, Damien Veyret. DEVELOPING LENGTHS IN WOVEN AND HELICAL HOLLOW TUBES FOR DEAN VORTICES FLOWS. Engineering Applications of Computational Fluid Mechanics, 2009. ⟨hal-01916728⟩ Plus de détails...
Philippe Moulin, Fanny Springer, Emilie Carretier, Damien Veyret. DEVELOPING LENGTHS IN WOVEN AND HELICAL HOLLOW TUBES FOR DEAN VORTICES FLOWS. Engineering Applications of Computational Fluid Mechanics, 2009. ⟨hal-01916728⟩
Journal: Engineering Applications of Computational Fluid Mechanics
Philippe Moulin, E. Carretier, M Moulin, M Beaujean, F Charbit. Purification and dehydration of methylal by pervaporation. Journal of Membrane Science, 2003, 217 (1-2), pp.159 - 171. ⟨10.1016/S0376-7388(03)00125-X⟩. ⟨hal-01888090⟩ Plus de détails...
Philippe Moulin, E. Carretier, M Moulin, M Beaujean, F Charbit. Purification and dehydration of methylal by pervaporation. Journal of Membrane Science, 2003, 217 (1-2), pp.159 - 171. ⟨10.1016/S0376-7388(03)00125-X⟩. ⟨hal-01888090⟩
